In its natural form (without any additives), natural as well as synthetic
rubber is useless as its consistency varies with temperature and its elasticity is lost in
prolonged tension. Thus the need for additives. Natural rubber usually comes in the form
of “ribbed smoked rubber sheets” in weights of 30-110kg
Synthetic rubber is used as a substitute for natural rubber. Historically, one
of the first synthetic variants was “Methyl-rubber” produced in Germany during the
1914-18 war. The raw materials used were coal and limestone (Germany, Russia). Others
experimented with other raw materials such as alcohol (U.S.A, Italy, Russia), petroleum
(U.S.A, Russia) and natural gas (Germany). A major breakthrough in synthetic rubber
evolution was the development of Buna S 3 during the 1939-45 war by Germany. On the
other hand in U.S.A, the variants were GR-S, Neoprene, Butyl rubber and GR-N (Buna
N). These synthetic variants virtually made the production of tyres possible without the
use of any natural rubber.
Natural rubber, styrene butadiene rubber(SBR) and polybutadiene rubber(BR) are
primarily used for tread and sidewalls. On the other hand butyl and halobutyl rubbers are
used in inner liners.
Synthetic rubber has some advantages over natural rubber in terms of physical
properties such as wear and abrasion resistance but there is no perfect synthetic
alternative to natural rubber. Nowadays synthetic rubber comes as oil-inclusive (paraffin
or aromatic oil), staining/non-staining, acrylonitrile based, styrene based and so on.
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